Electrochemical Behaviour Study of KF in Artificial Saliva Mediated by GCE Using Cyclic Voltammetry

doi:https://doi.org/10.48112/bcs.v2i3.474

Biomedicine and Chemical Sciences

2023, Volume 2, Issue 3 : 166-170 doi: https://doi.org/10.48112/bcs.v2i3.474

Research Article

Electrochemical Behaviour Study of KF in Artificial Saliva Mediated by GCE Using Cyclic Voltammetry

Noor Abdul Sahib Abass

Amal Abdul Latif Rashid

Muhammed Mizher Radhi

DOI : https://doi.org/10.48112/bcs.v2i3.474

Received

March 13, 2023

Revised

April 30, 2023

Accepted

April 30, 2023

Published

July 1, 2023

Abstract

A new study used potassium fluoride (KF) in different concentrations (2% and 5%), one of the components in the complete denture as supported material. The study aims to find the electrochemical analysis by cyclic voltammetric (CV) technique of the physical properties of this material and the influence in artificial saliva (AS) by oxidation–reduction peak current in the oral cavity. This study used a glassy carbon electrode (GCE) as a working electrode, Ag/AgCL as a reference electrode, and platinum wire as an auxiliary electrode in the cyclic voltammetry cell. Different physical properties such as concentration, pH, scan rate, and reproducibility study were used in the potential-state. The results showed two oxidation peaks current at 1.4 and 0.75 Volt characterize to the artificial saliva and KF respectively, and one reduction peak current at -0.5 Volt for KF. All peaks were enhanced by increasing the concentrations and scan rates that indicate the study in the right response. Using different pH, the oxidation peak of KF disappeared in alkaline pH and enhanced in an acidic medium, so the KF ions act as an oxidative reagent in artificial saliva of acidic pH, and antioxidant in alkaline pH at a limited concentration of KF in the cavity of the mouth. The low concentration of KF (2%) used in the component of total denture is more favourable than the high concentration (5%). In addition, it is better to store the total denture in an alkaline solution after use to avoid any damage to the mouth cells.

Keywords

Artificial Saliva

Cyclic Voltammetry

Redox

REFERENCES

Adair, S. M., Whitford, G. M., & Hanes, C. M. (1994). In vitro effect of human saliva on the output of fluoride from controlled-release devices. Pediatric dentistry, 16(6), 410-412.
Baliga, S., Muglikar, S., & Kale, R. (2013). Salivary pH: A diagnostic biomarker. Journal of Indian Society of Periodontology, 17(4), 461–465. https://doi.org/10.4103%2F0972-124X.118317
Brett, C. M., & Muresan, I. (2002). The influence of artificial body fluids on metallic corrosion. Key Engineering Materials, 230, 459-462. https://doi.org/10.4028/www.scientific.net/KEM.230-232.459
Hellwig, E., Polydorou, O., Lussi, A., Kielbassa, A. M., & Altenburger, M. J. (2010). The influence of saliva on the dissolution of calcium fluoride after application of different fluoride gels in vitro. Quintessence international, 41(9). https://boris.unibe.ch/id/eprint/408
Huang, H. H. (2002). Effect of chemical composition on the corrosion behavior of Ni‐Cr‐Mo dental casting alloys. Journal of Biomedical Materials Research, 60(3), 458-465. https://doi.org/10.1002/jbm.10080
Ibrahim, A. I., & Radhi, M. M. (2021, March). Electrochemical study of Fe II/Fe III on modified GCE with PAN and PMMA at different temperatures using cyclic voltammetry. In Journal of Physics: Conference Series (Vol. 1853, No. 1, p. 012008). IOP Publishing. https://doi.org/10.1088/1742-6596/1853/1/012008
Opydo-Szymaczek, J., Pawlaczyk-Kamieńska, T., & Borysewicz-Lewicka, M. (2022). Fluoride Intake and Salivary Fluoride Retention after Using High-Fluoride Toothpaste Followed by Post-Brushing Water Rinsing and Conventional (1400–1450 ppm) Fluoride Toothpastes Used without Rinsing. International Journal of Environmental Research and Public Health, 19(20), 13235. https://doi.org/10.3390/ijerph192013235
Radhi, M. M., & Al-Mulla, E. A. J. (2015). Use of a grafted polymer electrode to study mercury ions by cyclic voltammetry. Research on Chemical Intermediates, 41(3), 1413-1420. https://doi.org/10.1007/s11164-013-1282-1
Radhi, M. M., Abdullah, H. N., Al-Asadi, S. A., & Al-Mulla, E. A. J. (2015). Electrochemical oxidation effect of ascorbic acid on mercury ions in blood sample using cyclic voltammetry. International Journal of Industrial Chemistry, 6(4), 311-316. https://doi.org/10.1007/s40090-015-0053-9
Radhi, M. M., Abdullah, H. N., Al-Asadi, S. A., & Al-Mulla, E. A. J. (2015). Electrochemical oxidation effect of ascorbic acid on mercury ions in blood sample using cyclic voltammetry. International Journal of Industrial Chemistry, 6(4), 311-316. https://doi.org/10.1007/s40090-015-0053-9
Radhi, M. M., Abdullah, H. N., Jabir, M. S., & Al-Mulla, E. A. J. (2017). Electrochemical effect of ascorbic acid on redox current peaks of CoCl 2 in blood medium. Nano Biomedicine and Engineering, 9(2), 103-106. https://doi.org/10.5101/nbe.v9i2.p103-106
Radhi, M. M., Abdullah, H. N., Jabir, M. S., & Al-Mulla, E. A. J. (2017). Electrochemical effect of ascorbic acid on redox current peaks of CoCl 2 in blood medium. Nano Biomedicine and Engineering, 9(2), 103-106.
Radhi, M. M., Alosfur, F. K. M., & Ridha, N. J. (2018). Voltammetric characterization of grafted polymer modified with ZnO nanoparticles on glassy carbon electrode. Russian journal of electrochemistry, 54, 27-32. https://doi.org/10.1134/S1023193518010068
Radhi, M. M., Ibrahim, A. I., Al-Haidarie, Y. K., Al-Asadi, S. A., & Al-Mulla, E. A. J. (2019). Rifampicin: Electrochemical effect on blood component by cyclic voltammetry using nano-sensor. Nano Biomedicine and Engineering, 11(2), 150-156. https://doi.org/10.5101/nbe.v11i2.p150-156
Wang, H. W., Bringans, C., Hickey, A. J., Windsor, J. A., Kilmartin, P. A., & Phillips, A. R. (2021). Cyclic voltammetry in biological samples: a systematic review of methods and techniques applicable to clinical settings. Signals, 2(1), 138-158. https://doi.org/10.3390/signals2010012

Recommended Articles

Original Article Open Access

A FRAMEWORK OF MONOCLONAL ANTIBODIES AND RELATED PRODUCTION ENGINEERING

Navneet Kumar Verma

2025, Volume 4, Issue 4 : 26-34

Download PDF

Research Article Open Access

Investigation of Tritrichomonas Foetus in Cattle Using Different Methods in Basrah City – Iraq

Muntaha A. H. Nasir ,

Al-Idreesi S.R. ,

Wasfi A. Al-Masoudi

2023, Volume 2, Issue 1 : 39-43

DOI: https://doi.org/10.48112/bcs.v2i1.334

Download PDF

Research Article Open Access

The Role of Vitamin D and Zinc In Facing COVID-19 Injury

Yazi Abdullah Jassima

2022, Volume 1, Issue 1 : 6-10

DOI: https://doi.org/10.48112/bcs.v1i1.76

Download PDF

Research Article Open Access

Design and Synthesis Ligands Tetradents Substituted with Halogenes in α- Position and Conjugation with Riboflavin (Bioconjugates)

Nasser Thallaj

2022, Volume 1, Issue 2 : 47-56

DOI: https://doi.org/10.48112/bcs.v1i2.85

Download PDF

Biomedicine and Chemical Sciences journal thumbnail

Volume 2, Issue 3

Downloads

Download PDF xml

Download XML

Citations

2 Views

0 Downloads

Share this article

License

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

All papers should be submitted electronically. All submitted manuscripts must be original work that is not under submission at another journal or under consideration for publication in another form, such as a monograph or chapter of a book. Authors of submitted papers are obligated not to submit their paper for publication elsewhere until an editorial decision is rendered on their submission. Further, authors of accepted papers are prohibited from publishing the results in other publications that appear before the paper is published in the Journal unless they receive approval for doing so from the Editor-In-Chief.

Biomed. Chem. Sci. open access articles are licensed under a Creative Commons Attribution-ShareAlike 4.0 International License. This license lets the audience to give appropriate credit, provide a link to the license, and indicate if changes were made and if they remix, transform, or build upon the material, they must distribute contributions under the same license as the original.