Synthesis Nanoparticles of Copper and Dicopper Oxide via Change Atmosphere of Copper Ablation

doi:https://doi.org/10.48112/bcs.v2i3.488

Biomedicine and Chemical Sciences

2023, Volume 2, Issue 3 : 227-232 doi: https://doi.org/10.48112/bcs.v2i3.488

Research Article

Synthesis Nanoparticles of Copper and Dicopper Oxide via Change Atmosphere of Copper Ablation

Ahmed Hussein Mohammed Al-Antaki

DOI : https://doi.org/10.48112/bcs.v2i3.488

Received

March 31, 2023

Revised

April 12, 2023

Accepted

April 12, 2023

Published

July 1, 2023

Abstract

The fabrication technique to synthesis dicopper oxide nanoparticles (Cu₂ONPs) and copper nanoparticles (CuNPs) is laser ablation by a pure copper rod. To save the environmental system, we converted setup of device to develop the clean technology. In addition, the solvent using in both systems is water (green chemistry) without agent or surfactant. The average size of Cu₂ONPs is 20 nm via enclosed platform of air under 600 mJ of laser power for 1h. However, the average size is 12 nm to generate CuNPs under N₂ gas and 600 mJ of laser power for 1h. The morphology and the shape of the particles explain by Scanning Electron Microscope (SEM) images and Transmission Electron Microscopy (TEM) images. Also, the average size of the nanoparticles proved by measuring of 100 particles by using TEM image. In addition, The High-Resolution Transmission Electron Microscopy (HRTEM) image explains the distance between the layers in CuNPs which is 0.21 nm. The X-ray diffraction (XRD) and Attenuated Total Reflection-Fourier Transform Infrared (ATR-FTIR) of the product show the type of nanoparticles’ structure.

Keywords

Cu2ONPs

CuNPs

Green chemistry

Pulsed laser ablation

Pure copper rod

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